Gallium Crystal Chemistry in Synthetic Goethites

نویسندگان

  • F. Martin
  • P. Mathe
  • Y. Noack
  • O. Grauby
چکیده

The distribution of Ga and A1 atoms within the octahedral sheets of synthetic goethites has been investigated by XRD and Ga K-edge XANES and EXAFS spectroscopies. XRD results indic te a solid solution between goethite (aFeOOH) and GaGoe4 (40 mol% of Ga). The XANES data indicate the presence of &a in the solid solution. The fitting procedures for EXAFS spectra show no evidence of preferential octahedral site substitutions for Ga.

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تاریخ انتشار 2017